流态化法部分热解氯化镁制备镁水泥原料的研究   总被引：1，自引：0，他引：1       下载免费PDF全文

王世栋  都永生  孙庆国  李明珍  火焱 《盐湖研究》2010,18(1):42-45

探讨了影响流态化法热解水合氯化镁的主要因素,在进口温度750℃下,改变进料速度,可控地制备了不同摩尔比的镁水泥原料。  相似文献   

Probabilistic Durability Assessment of Concrete Structures in Marine Environments: Reliability and Sensitivity Analysis   总被引：1，自引：1，他引：0  

YU Bo  NING Chao-lie  LI Bing 《海洋工程》2017,31(1):63-73

A probabilistic framework for durability assessment of concrete structures in marine environments was proposed in terms of reliability and sensitivity analysis, which takes into account the uncertainties under the environmental, material, structural and executional conditions. A time-dependent probabilistic model of chloride ingress was established first to consider the variations in various governing parameters, such as the chloride concentration, chloride diffusion coefficient, and age factor. Then the Nataf transformation was adopted to transform the non-normal random variables from the original physical space into the independent standard Normal space. After that the durability limit state function and its gradient vector with respect to the original physical parameters were derived analytically, based on which the first-order reliability method was adopted to analyze the time-dependent reliability and parametric sensitivity of concrete structures in marine environments. The accuracy of the proposed method was verified by comparing with the second-order reliability method and the Monte Carlo simulation. Finally, the influences of environmental conditions, material properties, structural parameters and execution conditions on the time-dependent reliability of concrete structures in marine environments were also investigated. The proposed probabilistic framework can be implemented in the decision-making algorithm for the maintenance and repair of deteriorating concrete structures in marine environments.  相似文献   

Histological study on the skin of Japanese flounder <Emphasis Type="Italic">Paralichthys olivaceus</Emphasis>     

ZHUJie ZHANGXiumei GAOTianxiang 《中国海洋大学学报(英文版)》2005,4(2):145-151

Histological development of Japanese flounder Paralichthys olivaceus larval skin and ultrastructural difference of skin between reared normal and malpigmented Japanese flounder were studied with light microscopy (LM) and transmission electron microscopy (TEM). The results show that the skin develops slowly before the metamorphosis, while at the onset of metamorphosis, the skin develops quickly and becomes complete in structure till about 50d after being hatched. Ultrastructural observation on the normal and malpigmented skins shows that the iridophore and melanophore are adjacent to each other. Profile and structure of the two kinds of pigmcnt cells are more complete in the skin of normal ocular side than in the skin of pigmented blind side. The ultrastructure of typical chloride cell was observed in the skin of Japanese flounder larvae for the first time.  相似文献   

SIMULTANEOUS ANALYSIS OF Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ)AND Cd(Ⅱ)BY SPECTROPHOTOMETRY AND THE KALMAN FILTER     

LEMING SHI ZHILIANG LI ZHIHONG XU ZHONGXIAO PAN LESHAN WANG Laboratory of Computer Chemistry Institute of Chemical Metallurgy  Chinese Academy of Sciences  Beijing  P.R.China 《地理学报(英文版)》1991,(3)

This paper describes the simultaneous determination of cobalt,nickel,copper,zinc and cadmium byspectrophotometry and the Kalman filter method.Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ)and Cd(Ⅱ)react with 5-bromo-2-(2-pyridylazo)-5-diethylaminophenol(5-Br-PADAP)in the presence of cationic surfactant cetylpyridinium bromide(CPB)to form five different coloured ternary complexes.The absorption curves ofthese complexes overlap severely in the scanning range 500-620 nm.The Kalman filter algorithm issuccessfully applied to resolve the overlapped absorption curves and therefore makes the simultaneousdetermination of these metallic ions possible without tedious pretreatment.The proposed method isapplied to analyse the titled elements in synthetic samples and in environmental samples such as hair,fingernail and river water samples with satisfactory results.  相似文献   

Energetic Electrons as a Field Line Topology Tracer in the High Latitude Boundary/CUSP Region: Cluster Rapid Observations     

Q. G. Zong  T. A. Fritz  A. Korth  P. W. Daly  M. Dunlop  A. Balogh  J. F. Fennell  J. D. Sullivan  R. W. H. Friedel  H. Reme 《Surveys in Geophysics》2005,26(1-3):215-240

Energetic electrons (e.g., 50 keV) travel along field lines with a high speed of around 20 R_Es⁻¹. These swift electrons trace out field lines in the magnetosphere in a rather short time, and therefore can provide nearly instantaneous information about the changes in the field configuration in regions of geospace. The energetic electrons in the high latitude boundary regions (including the cusp) have been examined in detail by using Cluster/RAPID data for four consecutive high latitude/cusp crossings between 16 March and 19 March 2001. Energetic electrons with high and stable fluxes were observed in the time interval when the IMF had a predominately positive B_z component. These electrons appeared to be associated with a lower plasma density exhibiting no obvious tailward plasma flow (<20 keV). On the other hand, no electrons or only spike-like electron events have been observed in the cusp region during southward IMF. At that time, the plasma density was as high as that in the magnetosheath and was associated with a clear tailward flow. The fact that no stable energetic electron fluxes were observed during southward IMF indicates that the cusp has an open field line geometry. The observations indicate that both the South and North high latitude magnetospheric boundary regions (including both North and South cusp) can be energetic particle trapping regions. The energetic electron observations provide new ways to investigate the dynamic cusp processes. Finally, trajectory tracing of test particles has been performed using the Tsyganenko 96 model; this demonstrates that energetic particles (both ions and electrons) may be indeed trapped in the high latitude magnetosphere.  相似文献   

Ferric chloride treatment to control alakli induced heave in weathered red earth     

P. V. Sivapullaiah  Manju 《Geotechnical and Geological Engineering》2006,24(5):1115-1130

A detailed experimental investigation has been carried out to study the use of ferric chloride salt to control the undesirable volume changes induced by high concentrated alkali contamination on kaolinitic red earth. X-Ray diffraction studies have revealed that soil alkali interactions produce mineralogical changes and formation of new mineral such as zeolite, which are responsible for observed swelling in non-swelling kaolinitic soil. Loss of ferric oxide, which are known cementing agents has been attributed as one of the reasons for swelling in alkali contaminated soils. The consolidation behaviour of soil compacted with 5% ferric chloride solution by weight of solutions and inundated with alkali solutions as well as soil compacted with alkali and inundated with 5% ferric chloride by weight of solutions has been studied. To study the effect of amount of ferric chloride, the volume change behaviour of soil compacted with different weight percentages of ferric salts by weight of soil (1%, 3%, and 5%) and inundated with alkali solutions has also been studied. The swelling of soil compacted with alkali has been checked by inundating with 5% ferric chloride solutions due to neutralization of alkali and is not controlled when soil compacted with 5% ferric chloride solutions is inundated continuously with alkali solutions. Further, even when the soil is treated with higher amounts of ferric chloride, in the range of 1–5% by weight of soil, the swelling is not controlled. X-ray diffraction studies have shown that the formation of zeolite is not inhibited in the presence of ferric salts.This study clearly shows that ferric chloride treatment can overcome the effects of small concentrations of alkali; it is ineffective to overcome the large and continued exposure of soils with alkali contamination.  相似文献   

Photocatalytic Reduction of Cr^Ⅵ by Natural Sphalerite Suspensions under Visible Light Irradiation   总被引：4，自引：0，他引：4  

LI Yan LU Anhuai WANG Changqiu 《《地质学报》英文版》2006,80(2):267-272

The photocatalytic reductive capability of a natural semiconducting mineral, sphalerite has been studied for the first time. The sphalerite from the Huangshaping deposit of Hunan Province performed great photoreductive capability that 91.95% of the Cr^6＋ was reduced under 9 h visible light irradiation, higher than the 70.58% under 9.5 h UV light irradiation. The highly reductive ability results from its super negative potential of electrons in the conduction band. Furthermore, Fe substitution for Zn introduces donor states, and the oxidation process of Fe^2＋ to Fe^3＋ makes it an effective hole-scavenger. Cd and Cu substitute for Zn also reduce the bandgap and help broaden the absorbing edge towards the visible light. These substituting metal ions in natural sphalerite make it a hyper-active photocatalyst and very attractive for solar energy utilization.  相似文献   

Heavy Metal Removal from Water by Adsorption Using Pillared Montmorillonite   总被引：1，自引：0，他引：1  

LIU Yun WU Pingxiao DANG Zhi YE Daiqi 《《地质学报》英文版》2006,80(2):219-225

Removal of Cu^2＋, Cr^3＋ and Cd^2＋ from aqueous solutions by adsorption on montmorillonite modified by sodium dodecylsulfate （SDS） and hydroxy-alumino-silicate （HAS） was investigated. Experiments were carried out as a function of solution pH, solute concentration, and time. The Langmuir model was adopted to describe the single-solute adsorption isotherm, in which the Langmuir parameters were directly taken from those obtained in single-solute systems. The kinetics of metal ions adsorption was examined and the pseudo-first-order rate constant was finally evaluated.  相似文献   

Photocatalytic Reduction of Cr~Ⅳ by Natural Sphalerite Suspensions under Visible Light Irradiation     

LI Yan  LU Anhuai  WANG Changqiu School of Earth  Space Sciences  Peking University  Beijing 《《地质学报》英文版》2006,80(2)

The photocatalytic reductive capability of a natural semiconducting mineral, sphalerite has been studied for the first time. The sphalerite from the Huangshaping deposit of Hunan Province performed great photoreductive capability that 91.95% of the Cr6+ was reduced under 9 h visible light irradiation, higher than the 70.58% under 9.5 h UV light irradiation. The highly reductive ability results from its super negative potential of electrons in the conduction band. Furthermore, Fe substitution for Zn introduces donor states, and the oxidation process of Fe2+ to Fe3+ makes it an effective hole-scavenger. Cd and Cu substitute for Zn also reduce the bandgap and help broaden the absorbing edge towards the visible light. These substituting metal ions in natural sphalerite make it a hyper-active photocatalyst and very attractive for solar energy utilization.  相似文献   

A Case Study of Spectral and Non‐Spectral Interferences on Copper Isotope Measurements by Multi‐Collector ICP‐MS (Wet Plasma)     

Jérôme C. J. Petit  Aurélien Taillez  Nadine Mattielli 《Geostandards and Geoanalytical Research》2013,37(3):319-335

Mathematical modelling was combined with experimental Cu isotope measurements to demonstrate the effect of the sample matrix in changing the absolute and relative abundances of spectral interferences from Ti and Cr species. This unforeseen non‐spectral effect, evidenced by variable inaccuracies of the different Zn‐normalised Cu isotope ratios, was investigated by comparing real sedimentary samples and artificial solutions intended to match the Cu:Ti:Cr ratios of the real samples after (one or two step) chromatographic processing. Artificial solutions showed positive bias in δ⁶⁵Cu_X/Y with the magnitude depending on (a) the ^6XZn/^6YZn ratio used for normalisation, (b) the Ti/Cu ratio and (c) the transmission coefficient of the TiO species. In contrast, real samples showed different δ⁶⁵Cu_X/Y patterns and displayed a more complex population of Ti and Cr oxides and hydroxides, giving rise to positive and negative inaccuracies that were two to six times higher compared with the artificial samples. The results evidence contrasting behaviour of Ti and Cr when forming polyatomic species in the plasma and stress that artificial solutions may fail to predict how residual elements interact with the analyte/dopant pair during MC‐ICP‐MS analyses. More importantly, the study shows that all Zn isotope ratios do not have the same merit in correcting for mass bias in the presence of matrix elements and should all be monitored to verify the absence of spectral interferences for Cu isotope measurements. In this respect, accurate Cu data could be generally obtained by a two‐step chromatographic purification providing a minimum reduction of ~ 21000 and ~ 3000 times the initial amounts of Ti and Cr, respectively.  相似文献